Formaldehyde Oxime ⇌ Nitrosomethane Tautomerism.
نویسندگان
چکیده
منابع مشابه
CASPT2 study of the decomposition of nitrosomethane and its tautomerization reactions in the ground and low-lying excited states.
The dissociation reaction of nitrosomethane into methyl and nitric oxide and the tautomerization reactions to formaldehyde oxime, nitrone, and methoxy nitrene have been studied with the second-order multiconfigurational perturbation theory (CASPT2) by the computation of numerical energy gradients. The prevailing reactions in both the ground and the excited states are dissociations. The structur...
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 2002
ISSN: 0022-3263,1520-6904
DOI: 10.1021/jo0129529